Robust C–C bonded porous networks with chemically designed functionalities for improved CO2 capture from flue gas

by D. Thirion, J. S. Lee, E. Ozdemir, C. T. Yavuz
Year: 2016 DOI: 10.3762/bjoc.12.220

Extra Information

Invited Paper for the thematic issue on "Organic Porous Materials"


Effective carbon dioxide (CO2) capture requires solid, porous sorbents with chemically and thermally stable frameworks. Herein, we report two new carbon–carbon bonded porous networks that were synthesized through metal-free Knoevenagel nitrile–aldol condensation, namely the covalent organic polymer, COP-156 and 157. COP-156, due to high specific surface area (650 m2/g) and easily interchangeable nitrile groups, was modified post-synthetically into free amine- or amidoxime-containing networks. The modified COP-156-amine showed fast and increased CO2 uptake under simulated moist flue gas conditions compared to the starting network and usual industrial CO2 solvents, reaching up to 7.8 wt % uptake at 40 °C.


C–C bond CO2 capture microporous materials porous polymers postmodification